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Phosphorylated aminoacetal in the synthesis of new acyclic, cyclic, and heterocyclic polyphenol structures

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dc.contributor.author Vagapova L.
dc.contributor.author Burilov A.
dc.contributor.author Voronina J.
dc.contributor.author Syakaev V.
dc.contributor.author Sharafutdinova D.
dc.contributor.author Amirova L.
dc.contributor.author Pudovik M.
dc.contributor.author Garifzyanov A.
dc.contributor.author Sinyashin O.
dc.date.accessioned 2018-09-18T20:13:55Z
dc.date.available 2018-09-18T20:13:55Z
dc.date.issued 2014
dc.identifier.issn 1042-7163
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137782
dc.description.abstract New phosphorylated aminoacetal has been synthesized by the Kabachnik-Fields reaction; its reactivity has been studied in acid-catalyzed condensation with linear polyphenols (2-methylresorcinol, resorcinol, pyrogallol) and the Mannich reaction with macrocyclic polyphenol (calix[4]resorcinol). It has been determined for the first time that acid-catalyzed reaction of phosphorus-containing acetal with resorcinol and its derivatives in ethanol in the presence of hydrochloric acid gives new phosphorylated piperazines in addition to the compounds of diarylmethane series. Condensation of macrocyclic polyphenol (calix[4]resorcinol) with formaldehyde and N-((dihexylphosphoryl) methyl)-2, 2-dimethoxyethylamine (the Mannich reaction) has resulted in novel tetrasubstituted calixarene containing aminophosphine oxide and acetal groups on the "upper rim" of molecule. © 2014 Wiley Periodicals, Inc.
dc.relation.ispartofseries Heteroatom Chemistry
dc.title Phosphorylated aminoacetal in the synthesis of new acyclic, cyclic, and heterocyclic polyphenol structures
dc.type Article
dc.relation.ispartofseries-issue 3
dc.relation.ispartofseries-volume 25
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 178
dc.source.id SCOPUS10427163-2014-25-3-SID84900839979


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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