dc.contributor.author |
Nizamov I. |
|
dc.contributor.author |
Bolshakova O. |
|
dc.contributor.author |
Al'metkina L. |
|
dc.contributor.author |
Sergeenko G. |
|
dc.contributor.author |
Frolova L. |
|
dc.contributor.author |
Krivolapov D. |
|
dc.contributor.author |
Batyeva E. |
|
dc.contributor.author |
Litvinov I. |
|
dc.date.accessioned |
2018-09-18T20:13:54Z |
|
dc.date.available |
2018-09-18T20:13:54Z |
|
dc.date.issued |
2006 |
|
dc.identifier.issn |
1042-7163 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/137778 |
|
dc.description.abstract |
S-(Diethylamino)dimethylsilyl bis(diethylamido)dithiophosphate 3 was obtained by the reaction of tetraphosphorus decasulfide 1 with bis(diethylamino)dimethylsilane 2a. The reactions of Lawesson's reagent 5 with 2a and the alkyl homologues of Davy's reagent 8a,b with trimethyl(diethylamino) silane 6 were studied. On the basis of these reactions, methods of synthesizing S-(diethylamino)dimethylsilyl or S-(diethylamino)-diphenylsilyl 4-methoxyphenyl (diethylamido)dithiophosphonates 7a and 7b and S-trimethylsilyl S-alkyl(diethylamido)tnthiophosphates 9a,b are described. The optimal reaction conditions and thermal stability of S-trimethylsilyl S-ethyl(diethylamido) trithiophosphate 9a were defined by differential thermal analyses. Compound 9a have been decomposed to form 2,4-bis(diethylamido)-1,3,2,4-dithiadiphosphetane- 2,4-disulfide 10 which structure was established by X-ray single crystal diffraction. © 2006 Wiley Periodicals, Inc. |
|
dc.relation.ispartofseries |
Heteroatom Chemistry |
|
dc.title |
Synthesis and thermal stability of S-trimethylsilyl esters of tetracoordinated phosphorus amidothioacids |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
7 |
|
dc.relation.ispartofseries-volume |
17 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
670 |
|
dc.source.id |
SCOPUS10427163-2006-17-7-SID33845390030 |
|