Mechanism of the Reactions of (2,2-Dimethyl-1-((Trimethylsilyl)Oxy)Propylidene)-(Trimethylsilyl)Phosphine with Nucleophilic and Electrophilic Reagents

dc.contributor.author	Vereshchagina Y.
dc.contributor.author	Alimova A.
dc.contributor.author	Chachkov D.
dc.contributor.author	Ishmaeva E.
dc.date.accessioned	2018-09-18T20:13:52Z
dc.date.available	2018-09-18T20:13:52Z
dc.date.issued	2015
dc.identifier.issn	1042-6507
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/137774
dc.description.abstract	Copyright © 2015 Taylor & Francis Group, LLC. The mechanism of the reaction of 3,3-dimethyl-2-trimethylsiloxy-1-trimethylsilyl-1-phosphabut-1-ene with bis(phenylendioxy)chlorophosphorane was studied by the density functional theory method. According to the quantum chemical calculations this interaction occurs in parallel on two reaction centers: PII atom (electrophilic substitution) and O atom (nucleophilic substitution).
dc.relation.ispartofseries	Phosphorus, Sulfur and Silicon and the Related Elements
dc.subject	electrophilic substitution
dc.subject	halogenophosphoranes
dc.subject	nucleophilic substitution
dc.subject	Phosphaalkenes
dc.subject	quantum chemical calculations
dc.subject	reaction mechanism
dc.title	Mechanism of the Reactions of (2,2-Dimethyl-1-((Trimethylsilyl)Oxy)Propylidene)-(Trimethylsilyl)Phosphine with Nucleophilic and Electrophilic Reagents
dc.type	Article
dc.relation.ispartofseries-issue	5-6
dc.relation.ispartofseries-volume	190
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	918
dc.source.id	SCOPUS10426507-2015-190-5-6-SID84953889275

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.