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Solid-Contact Potentiometric Sensor Based on Polyaniline and Unsubstituted Pillar[5]Arene

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dc.contributor.author Stoikova E.
dc.contributor.author Sorvin M.
dc.contributor.author Shurpik D.
dc.contributor.author Budnikov H.
dc.contributor.author Stoikov I.
dc.contributor.author Evtugyn G.
dc.date.accessioned 2018-09-18T20:13:25Z
dc.date.available 2018-09-18T20:13:25Z
dc.date.issued 2015
dc.identifier.issn 1040-0397
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137710
dc.description.abstract © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A novel potentiometric sensor based on screen-printed carbon electrode covered with electropolymerized polyaniline (PANI) and unsubstituted pillar[5]arene as ionophore has been developed and tested in potentiometric measurements of pH and metal ions. The introduction of pillar[5]arene improved the reversibility of the pH response in the range from 2.0 to 9.0 with the slope of 45mV/pH. Among metal cations, the response to Fe<sup>3+</sup> and Ag<sup>+</sup> ions was referred to PANI redox conversion whereas the signal toward Cu<sup>2+</sup> in the range from 1.0×10<sup>-6</sup> to 1.0×10<sup>-2</sup>M (limit of detection (LOD) 3.0×10<sup>-7</sup>M) to specific interaction with the macrocycle.
dc.relation.ispartofseries Electroanalysis
dc.subject Electropolymerization
dc.subject Pillar[5]arene
dc.subject Polyaniline
dc.subject Potentiometric sensor
dc.subject Solid-contact sensor
dc.title Solid-Contact Potentiometric Sensor Based on Polyaniline and Unsubstituted Pillar[5]Arene
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 27
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 440
dc.source.id SCOPUS10400397-2015-27-2-SID84931564767


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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