dc.contributor.author |
Stoikova E. |
|
dc.contributor.author |
Sorvin M. |
|
dc.contributor.author |
Shurpik D. |
|
dc.contributor.author |
Budnikov H. |
|
dc.contributor.author |
Stoikov I. |
|
dc.contributor.author |
Evtugyn G. |
|
dc.date.accessioned |
2018-09-18T20:13:25Z |
|
dc.date.available |
2018-09-18T20:13:25Z |
|
dc.date.issued |
2015 |
|
dc.identifier.issn |
1040-0397 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/137710 |
|
dc.description.abstract |
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A novel potentiometric sensor based on screen-printed carbon electrode covered with electropolymerized polyaniline (PANI) and unsubstituted pillar[5]arene as ionophore has been developed and tested in potentiometric measurements of pH and metal ions. The introduction of pillar[5]arene improved the reversibility of the pH response in the range from 2.0 to 9.0 with the slope of 45mV/pH. Among metal cations, the response to Fe<sup>3+</sup> and Ag<sup>+</sup> ions was referred to PANI redox conversion whereas the signal toward Cu<sup>2+</sup> in the range from 1.0×10<sup>-6</sup> to 1.0×10<sup>-2</sup>M (limit of detection (LOD) 3.0×10<sup>-7</sup>M) to specific interaction with the macrocycle. |
|
dc.relation.ispartofseries |
Electroanalysis |
|
dc.subject |
Electropolymerization |
|
dc.subject |
Pillar[5]arene |
|
dc.subject |
Polyaniline |
|
dc.subject |
Potentiometric sensor |
|
dc.subject |
Solid-contact sensor |
|
dc.title |
Solid-Contact Potentiometric Sensor Based on Polyaniline and Unsubstituted Pillar[5]Arene |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2 |
|
dc.relation.ispartofseries-volume |
27 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
440 |
|
dc.source.id |
SCOPUS10400397-2015-27-2-SID84931564767 |
|