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Electrochemical properties and reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine)

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dc.contributor.author Sakhapov I.
dc.contributor.author Gafurov Z.
dc.contributor.author Babaev V.
dc.contributor.author Kurmaz V.
dc.contributor.author Mukhametbareev R.
dc.contributor.author Rizvanov I.
dc.contributor.author Sinyashin O.
dc.contributor.author Yakhvarov D.
dc.date.accessioned 2018-09-18T20:13:03Z
dc.date.available 2018-09-18T20:13:03Z
dc.date.issued 2015
dc.identifier.issn 1023-1935
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137662
dc.description.abstract © 2015, Pleiades Publishing, Ltd. Electrochemical properties and reactivity of electrochemically activated forms of organonickel sigma-complex [NiBr(Mes)(bpy)] (where Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine) were studied. The activation of the organonickel sigma-complex was found to proceed under both electrochemical reduction and oxidation conditions to give coordinatively unsaturated forms of the complex: radical [Ni(Mes)(bpy)]• and cationic complex [Ni(Mes)(bpy)]+, respectively. It was shown experimentally that the active forms of organonickel complex [NiBr(Mes)(bpy)] can react with organic substrates (cyclohexene, octene-1, tetrahydrofuran) and convert nitriles (acetonitrile, acetonitrile-d3, chloroacetonitrile) into corresponding imines containing 2,4,6-trimethylphenyl fragment.
dc.relation.ispartofseries Russian Journal of Electrochemistry
dc.subject 2,2′-bipyridine
dc.subject cyclic voltammetry
dc.subject mass spectrometry
dc.subject organonickel sigma-complexes
dc.subject oxidation
dc.subject reduction
dc.title Electrochemical properties and reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine)
dc.type Article
dc.relation.ispartofseries-issue 11
dc.relation.ispartofseries-volume 51
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1061
dc.source.id SCOPUS10231935-2015-51-11-SID84947586957


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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