dc.contributor.author |
Remizov A. |
|
dc.contributor.author |
Kamalova D. |
|
dc.date.accessioned |
2018-09-18T20:12:01Z |
|
dc.date.available |
2018-09-18T20:12:01Z |
|
dc.date.issued |
2007 |
|
dc.identifier.issn |
0965-545X |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/137495 |
|
dc.description.abstract |
The behavior of probe molecules of different sizes (1,2-bromofluoroethane, 1,2-dichloroethane, dichloromethoxyphosphine oxide, 1,2-di-p-bromophenylethane) in PMMA and PVAC was considered. There is a linear correlation between the freezing temperature of conformational transitions of probe molecules and the size of the rotating groups of the probe. Processes that lead to the freezing-in of conformational equilibria of probes in polymers with a decrease in temperature are discussed on the basis of these results. The free-volume distribution and the nature of secondary relaxation processes in glassy polyvinyltrimethylsilane and polytrimethylsilylpropyne were studied by means of the conformation-probe technique. © Nauka/Interperiodica 2007. |
|
dc.relation.ispartofseries |
Polymer Science - Series A |
|
dc.title |
Freezing-in of molecular mobility of small molecules (probes) in glassy polymers and secondary relaxation transitions |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
49 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
503 |
|
dc.source.id |
SCOPUS0965545X-2007-49-5-SID34249907607 |
|