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dc.contributor.author | Remizov A. | |
dc.contributor.author | Kamalova D. | |
dc.date.accessioned | 2018-09-18T20:12:01Z | |
dc.date.available | 2018-09-18T20:12:01Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0965-545X | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/137495 | |
dc.description.abstract | The behavior of probe molecules of different sizes (1,2-bromofluoroethane, 1,2-dichloroethane, dichloromethoxyphosphine oxide, 1,2-di-p-bromophenylethane) in PMMA and PVAC was considered. There is a linear correlation between the freezing temperature of conformational transitions of probe molecules and the size of the rotating groups of the probe. Processes that lead to the freezing-in of conformational equilibria of probes in polymers with a decrease in temperature are discussed on the basis of these results. The free-volume distribution and the nature of secondary relaxation processes in glassy polyvinyltrimethylsilane and polytrimethylsilylpropyne were studied by means of the conformation-probe technique. © Nauka/Interperiodica 2007. | |
dc.relation.ispartofseries | Polymer Science - Series A | |
dc.title | Freezing-in of molecular mobility of small molecules (probes) in glassy polymers and secondary relaxation transitions | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 5 | |
dc.relation.ispartofseries-volume | 49 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 503 | |
dc.source.id | SCOPUS0965545X-2007-49-5-SID34249907607 |