Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide)

dc.contributor.author	Tatarinov D.
dc.contributor.author	Mironov V.
dc.contributor.author	Varaksina E.
dc.contributor.author	Krivolapov D.
dc.contributor.author	Litvinov I.
dc.contributor.author	Musin R.
dc.contributor.author	Buzykin B.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-18T20:11:30Z
dc.date.available	2018-09-18T20:11:30Z
dc.date.issued	2008
dc.identifier.issn	0959-9436
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/137424
dc.description.abstract	The reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with ethyl- and phenylmagnesium bromides and tetramethylenebis(magnesium bromide) is a versatile approach to the synthesis of unsymmetrical phosphine oxides. With the latter Grignard reagent, an unusual phosphorus-carbon cleavage also occurs to yield a pentacoordinate phosphorus derivative, 2,3,8,9-bis(4-chlorobenzo)-6-cyclohexyl-6,9-diphenyl-1,7-dioxa-6-phosphaspiro[5.5]deca-1,9-diene. © 2008.
dc.relation.ispartofseries	Mendeleev Communications
dc.title	Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide)
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	18
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	147
dc.source.id	SCOPUS09599436-2008-18-3-SID44649176418

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.