dc.contributor.author |
Latypov S. |
|
dc.contributor.author |
Epifanova N. |
|
dc.contributor.author |
Popova E. |
|
dc.contributor.author |
Vasilevsky S. |
|
dc.contributor.author |
Solovieva S. |
|
dc.contributor.author |
Antipin I. |
|
dc.contributor.author |
Konovalov A. |
|
dc.date.accessioned |
2018-09-18T20:10:48Z |
|
dc.date.available |
2018-09-18T20:10:48Z |
|
dc.date.issued |
2011 |
|
dc.identifier.issn |
0937-9347 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/137317 |
|
dc.description.abstract |
The combined application of two-dimensional nuclear magnetic resonance (2-D NMR) correlation experiments and gauge-including atomic orbital (GIAO) 13C NMR chemical shift calculations allowed reliable and simple determination of regioisomeric structure of heterocyclic substituents on the calix[4]arene lower rim. Moreover, the 1-D double pulsed field gradient nuclear Overhauser effect technique allows quick and efficient measurement of small nuclear Overhauser effects and, in doing so, establishes a 3-D structure of calix[4]arene simply and unequivocally. In general, these methods may find application in the regio- and stereoisomeric structure determination of complicated macrocyclic compounds. © 2011 Springer-Verlag. |
|
dc.relation.ispartofseries |
Applied Magnetic Resonance |
|
dc.title |
Combined Use of 2-D NMR Correlation Experiments, GIAO DFT 13C Chemical Shifts and 1-D NOESY Methods in Regioisomeric and Conformational Structure Determination of Cyclophanes in Solution |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2-4 |
|
dc.relation.ispartofseries-volume |
41 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
467 |
|
dc.source.id |
SCOPUS09379347-2011-41-24-SID81155135229 |
|