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pH-driven variation of the outer-sphere binding mode of cis-[Co(Ad)(en)2Cl]Cl (en-ethylendiamine, ad-adeninate) with p-sulfonatothiacalix[4]arene
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| dc.contributor.author | Skripacheva V. | |
| dc.contributor.author | Mustafina A. | |
| dc.contributor.author | Burilov V. | |
| dc.contributor.author | Galiullina L. | |
| dc.contributor.author | Latypov S. | |
| dc.contributor.author | Solov'eva S. | |
| dc.contributor.author | Antipin I. | |
| dc.contributor.author | Konovalov A. | |
| dc.date.accessioned | 2018-09-18T20:10:13Z | |
| dc.date.available | 2018-09-18T20:10:13Z | |
| dc.date.issued | 2006 | |
| dc.identifier.issn | 0923-0750 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/137219 | |
| dc.description.abstract | The non-symmetrical cobalt (III) complex cis-[Co(Ad)(en)2Cl]Cl (1Cl), possessing two flexible ethylendiaminate chelate rings (en) and monodentate N(9)-bound adeninate (Ad-) was chosen as the guest of p-sulfonatothiacalix[4]arene (STCA) to study the inclusion complex formation at wide range of pH 2-10. It was shown by 1H, NOE NMR methods and pH-metric procedure, that pH-driven variation of the inclusion mode of 1 + into calixarene cavity is the result of the protonation of 1 + via adeninate moiety. © 2006 Springer Science+Business Media, Inc. | |
| dc.relation.ispartofseries | Journal of Inclusion Phenomena and Macrocyclic Chemistry | |
| dc.subject | Co (III) bis-ethylendiaminate-adeninate | |
| dc.subject | Inclusion complex | |
| dc.subject | NMR 1H spectroscopy | |
| dc.subject | Outer-sphere coordination | |
| dc.subject | p-Sulfonatothiacalix[4]arene | |
| dc.title | pH-driven variation of the outer-sphere binding mode of cis-[Co(Ad)(en)2Cl]Cl (en-ethylendiamine, ad-adeninate) with p-sulfonatothiacalix[4]arene | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 3-4 | |
| dc.relation.ispartofseries-volume | 56 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 369 | |
| dc.source.id | SCOPUS09230750-2006-56-34-SID33846437897 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.