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dc.contributor.author | Andreyko E. | |
dc.contributor.author | Padnya P. | |
dc.contributor.author | Stoikov I. | |
dc.date.accessioned | 2018-09-18T20:09:59Z | |
dc.date.available | 2018-09-18T20:09:59Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0894-3230 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/137180 | |
dc.description.abstract | Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd. The formation of supramolecular associates based on water-soluble p-tert-butylthiacalix[4]arenes with amino acids has been studied. It was shown that amphiphilic p-tert-butylthiacalix[4]arenes preferably formed supramolecular associates with aromatic α-amino acids (tyrosine and tryptophan). Increasing size of the substituents of p-tert-butylthiacalix[4]arenes led to increase molecular weight of supramolecular associates based on the macrocycles and "guest" molecules. The spatial structures of p-tert-butylthiacalix[4]arenes and their associates with phenylalanine were studied by two-dimensional <sup>1</sup>H-<sup>1</sup>H nuclear Overhauser effect NMR spectroscopy. The ability of aggregates based on p-tert-butylthiacalix[4]arenes and amino acids to effectively interact with bovine serum albumin with the formation of 7- to 8-nm nanoparticles was shown. | |
dc.relation.ispartofseries | Journal of Physical Organic Chemistry | |
dc.subject | associates | |
dc.subject | molecular recognition | |
dc.subject | proteins | |
dc.subject | supramolecular chemistry | |
dc.subject | synthetic receptors | |
dc.subject | thiacalix[4]arenes | |
dc.title | Amphiphilic p-tert-butylthiacalix[4]arenes containing quaternary ammonium groups: From small molecules toward water-soluble nanoscale associates | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 8 | |
dc.relation.ispartofseries-volume | 28 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 527 | |
dc.source.id | SCOPUS08943230-2015-28-8-SID84937813621 |