dc.contributor.author |
Andreyko E. |
|
dc.contributor.author |
Padnya P. |
|
dc.contributor.author |
Stoikov I. |
|
dc.date.accessioned |
2018-09-18T20:09:59Z |
|
dc.date.available |
2018-09-18T20:09:59Z |
|
dc.date.issued |
2015 |
|
dc.identifier.issn |
0894-3230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/137180 |
|
dc.description.abstract |
Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd. The formation of supramolecular associates based on water-soluble p-tert-butylthiacalix[4]arenes with amino acids has been studied. It was shown that amphiphilic p-tert-butylthiacalix[4]arenes preferably formed supramolecular associates with aromatic α-amino acids (tyrosine and tryptophan). Increasing size of the substituents of p-tert-butylthiacalix[4]arenes led to increase molecular weight of supramolecular associates based on the macrocycles and "guest" molecules. The spatial structures of p-tert-butylthiacalix[4]arenes and their associates with phenylalanine were studied by two-dimensional <sup>1</sup>H-<sup>1</sup>H nuclear Overhauser effect NMR spectroscopy. The ability of aggregates based on p-tert-butylthiacalix[4]arenes and amino acids to effectively interact with bovine serum albumin with the formation of 7- to 8-nm nanoparticles was shown. |
|
dc.relation.ispartofseries |
Journal of Physical Organic Chemistry |
|
dc.subject |
associates |
|
dc.subject |
molecular recognition |
|
dc.subject |
proteins |
|
dc.subject |
supramolecular chemistry |
|
dc.subject |
synthetic receptors |
|
dc.subject |
thiacalix[4]arenes |
|
dc.title |
Amphiphilic p-tert-butylthiacalix[4]arenes containing quaternary ammonium groups: From small molecules toward water-soluble nanoscale associates |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
8 |
|
dc.relation.ispartofseries-volume |
28 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
527 |
|
dc.source.id |
SCOPUS08943230-2015-28-8-SID84937813621 |
|