Mechanistic aspects of reactions of triphenylphosphine with electron-deficient alkenes in acetic acid solution

dc.contributor.author	Salin A.
dc.contributor.author	Fatkhutdinov A.
dc.contributor.author	Il'In A.
dc.contributor.author	Sotov E.
dc.contributor.author	Sobanov A.
dc.contributor.author	Galkin V.
dc.contributor.author	James B.
dc.date.accessioned	2018-09-18T20:09:58Z
dc.date.available	2018-09-18T20:09:58Z
dc.date.issued	2013
dc.identifier.issn	0894-3230
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/137177
dc.description.abstract	Kinetic data provide evidence that proton transfer to the carbanion centre of a phosphonium zwitterion is the rate-determining step in quarternization reactions of triphenylphosphine with electron-deficient alkenes in acetic acid solution. This conclusion is based on the third-order rate equation, the reactivity of the alkenes, and solvent isotope effects in deuteroacetic acid. Copyright © 2013 John Wiley & Sons, Ltd.
dc.relation.ispartofseries	Journal of Physical Organic Chemistry
dc.subject	phosphonium zwitterions
dc.subject	proton transfer
dc.subject	rate-determining step
dc.subject	reaction mechanism
dc.subject	solvent isotope effect
dc.title	Mechanistic aspects of reactions of triphenylphosphine with electron-deficient alkenes in acetic acid solution
dc.type	Article
dc.relation.ispartofseries-issue	8
dc.relation.ispartofseries-volume	26
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	675
dc.source.id	SCOPUS08943230-2013-26-8-SID84880278546

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.