Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate

dc.contributor.author	Iskhakova G.
dc.contributor.author	Kiselev V.
dc.contributor.author	Van Eldik R.
dc.contributor.author	Zahl A.
dc.contributor.author	Shihab M.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-18T20:09:57Z
dc.date.available	2018-09-18T20:09:57Z
dc.date.issued	2011
dc.identifier.issn	0894-3230
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/137172
dc.description.abstract	Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate at 298.2 K are reported. This equilibrium is shifted to the phosphobetaine in polar solvents, salt solutions and under high external pressure. The reaction volume changes dramatically on going from less polar diethyl ether (-69 cm3 mol-1) and tetrahydrofurane (THF) (-66 cm3 mol -1), to more polar acetonitrile (-39 cm3 mol-1) and acetone (-38 cm3 mol-1). Copyright © 2010 John Wiley & Sons, Ltd.
dc.relation.ispartofseries	Journal of Physical Organic Chemistry
dc.subject	activation volume
dc.subject	reaction volume
dc.subject	solvent effect
dc.subject	tri-n- butylphosphoniumdithiocarboxylate
dc.title	Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate
dc.type	Article
dc.relation.ispartofseries-issue	5
dc.relation.ispartofseries-volume	24
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	360
dc.source.id	SCOPUS08943230-2011-24-5-SID79955056454

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.