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Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate

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dc.contributor.author Iskhakova G.
dc.contributor.author Kiselev V.
dc.contributor.author Van Eldik R.
dc.contributor.author Zahl A.
dc.contributor.author Shihab M.
dc.contributor.author Konovalov A.
dc.date.accessioned 2018-09-18T20:09:57Z
dc.date.available 2018-09-18T20:09:57Z
dc.date.issued 2011
dc.identifier.issn 0894-3230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137172
dc.description.abstract Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate at 298.2 K are reported. This equilibrium is shifted to the phosphobetaine in polar solvents, salt solutions and under high external pressure. The reaction volume changes dramatically on going from less polar diethyl ether (-69 cm3 mol-1) and tetrahydrofurane (THF) (-66 cm3 mol -1), to more polar acetonitrile (-39 cm3 mol-1) and acetone (-38 cm3 mol-1). Copyright © 2010 John Wiley & Sons, Ltd.
dc.relation.ispartofseries Journal of Physical Organic Chemistry
dc.subject activation volume
dc.subject reaction volume
dc.subject solvent effect
dc.subject tri-n- butylphosphoniumdithiocarboxylate
dc.title Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 24
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 360
dc.source.id SCOPUS08943230-2011-24-5-SID79955056454


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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