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Enthalpies of solution and partial molar volumes of magnesium perchlorate in alcohols and salt effect of acceleration of the Diels-Alder reaction

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dc.contributor.author Kiselev V.
dc.contributor.author Bolotov A.
dc.contributor.author Kashaeva H.
dc.contributor.author Potapova L.
dc.contributor.author Shakirova I.
dc.contributor.author Konovalov A.
dc.date.accessioned 2018-09-18T20:09:12Z
dc.date.available 2018-09-18T20:09:12Z
dc.date.issued 2011
dc.identifier.issn 0378-3812
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137039
dc.description.abstract Densities and enthalpies of solution at 25°C were measured for dilute solutions of magnesium perchlorate (MP) in some alcohols using the Anton Paar DSA 5000M vibrating tube densimeter and differential calorimetric measurements. In all studied solvents the solution of MP was highly exothermic and large solvent volume contraction was observed. Maximum effect was obtained in methanol and ethanol solutions. Acceleration effect of the Diels-Alder reaction of 9,10-dimethylanthracene with acrylonitrile (in medium of acrylonitrile) in the presence of salts LiClO4, Mg(ClO4)2 and GaCl3 was as 18:160:59,000. © 2011 Elsevier B.V.
dc.relation.ispartofseries Fluid Phase Equilibria
dc.subject Acceleration salt effect
dc.subject Density
dc.subject Enthalpy of solution
dc.subject Magnesium perchlorate
dc.subject Partial molar volume
dc.title Enthalpies of solution and partial molar volumes of magnesium perchlorate in alcohols and salt effect of acceleration of the Diels-Alder reaction
dc.type Article
dc.relation.ispartofseries-issue 1
dc.relation.ispartofseries-volume 312
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1
dc.source.id SCOPUS03783812-2011-312-1-SID80054756099


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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