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dc.contributor.author | Safin D. | |
dc.contributor.author | Bolte M. | |
dc.contributor.author | Babashkina M. | |
dc.date.accessioned | 2018-09-18T20:08:48Z | |
dc.date.available | 2018-09-18T20:08:48Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0340-4285 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/136963 | |
dc.description.abstract | Reaction of the potassium salts of N-(thio)phosphorylated thioureas of common formula AdNHC(S)N(H)P(X)(OiPr)2 (Ad = adamantyl; X = O, HL I ; X = S, HL II ) with Co(II), Zn(II), and Cd(II) cations in aqueous EtOH leads to M(L I,II -X, S) 2 chelate complexes. The Cd(II) complex Cd(L I ) 2 could not be isolated under analogous conditions because of its hydrolytic lability. The structure of the resulting compounds was studied by means of spectroscopy and microanalysis; in addition, the molecular structure of the complex Co(L II ) 2 was elucidated by single crystal X-ray diffraction analysis. The cobalt atom is in a tetrahedral S4 environment formed by the C=S and P=S sulfur atoms of two deprotonated ligands L II . The magnetic properties of Co(L I,II ) 2 were investigated and the photoluminescent properties of the complexes are also reported. © 2008 Springer Science+Business Media B.V. | |
dc.relation.ispartofseries | Transition Metal Chemistry | |
dc.title | Complexes of N-(thio)phosphorylthioureas AdNHC(S)NHP(X)(OiPr)2 (X = O, S) with cobalt(II), zinc(II), and cadmium(II). Crystal structure of Co[AdNHC(S)NP(S)(OiPr)2]2 | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 1 | |
dc.relation.ispartofseries-volume | 34 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 43 | |
dc.source.id | SCOPUS03404285-2009-34-1-SID57849113457 |