dc.contributor.author |
Safin D. |
|
dc.contributor.author |
Bolte M. |
|
dc.contributor.author |
Babashkina M. |
|
dc.date.accessioned |
2018-09-18T20:08:48Z |
|
dc.date.available |
2018-09-18T20:08:48Z |
|
dc.date.issued |
2009 |
|
dc.identifier.issn |
0340-4285 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/136963 |
|
dc.description.abstract |
Reaction of the potassium salts of N-(thio)phosphorylated thioureas of common formula AdNHC(S)N(H)P(X)(OiPr)2 (Ad = adamantyl; X = O, HL I ; X = S, HL II ) with Co(II), Zn(II), and Cd(II) cations in aqueous EtOH leads to M(L I,II -X, S) 2 chelate complexes. The Cd(II) complex Cd(L I ) 2 could not be isolated under analogous conditions because of its hydrolytic lability. The structure of the resulting compounds was studied by means of spectroscopy and microanalysis; in addition, the molecular structure of the complex Co(L II ) 2 was elucidated by single crystal X-ray diffraction analysis. The cobalt atom is in a tetrahedral S4 environment formed by the C=S and P=S sulfur atoms of two deprotonated ligands L II . The magnetic properties of Co(L I,II ) 2 were investigated and the photoluminescent properties of the complexes are also reported. © 2008 Springer Science+Business Media B.V. |
|
dc.relation.ispartofseries |
Transition Metal Chemistry |
|
dc.title |
Complexes of N-(thio)phosphorylthioureas AdNHC(S)NHP(X)(OiPr)2 (X = O, S) with cobalt(II), zinc(II), and cadmium(II). Crystal structure of Co[AdNHC(S)NP(S)(OiPr)2]2 |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.relation.ispartofseries-volume |
34 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
43 |
|
dc.source.id |
SCOPUS03404285-2009-34-1-SID57849113457 |
|