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dc.contributor.author | Mikhailov O. | |
dc.contributor.author | Kazymova M. | |
dc.contributor.author | Shumilova T. | |
dc.date.accessioned | 2018-09-18T20:08:47Z | |
dc.date.available | 2018-09-18T20:08:47Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0340-4285 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/136960 | |
dc.description.abstract | The complexing processes in the CuII-1,2-diaminoethanedithione- 1,2-ethanedione-1,2 and CuII-1,2-diaminoethanedithione-1,2- butanedione-2,3 triple systems occuring in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous alkaline solutions (pH~12) containing 1,2-diaminoethanedithione-1,2 and ethanedione-1,2 or butanedione-1,2 under room temperature, and between MCl2, 1,2-diaminoethanedithione- 1,2 and ethanedione-1,2 or butanedione-1,2 in the ethanol solutions, upon heating up to ~80 °C, have been studied. In both systems indicated, template synthesis occurs in the gelatin-immobililized matrix but does not occur in the ethanol solution. As a result of template synthesis, macrocyclic CuII chelates with 2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8 and its 4,5-dimethylsubstituted derivative are formed in the gelatin-immobililized matrix. 1,2-diaminoethanedithione-1,2 and ethanedione-1,2 or butanedione-2,3 are the ligand synthons in the processes indicated. © 2007 Springer. | |
dc.relation.ispartofseries | Transition Metal Chemistry | |
dc.title | Mild template synthesis of copper(II)-containing macrocyclic compounds in the CuII-1,2-diaminoethanedithione-1,2-ethanedione-1,2 and Cu II-1,2-diamino-ethanedithione-1,2-butanedione-2,3 triple systems into Cu2[Fe(CN)6]-gelatin-immobilized matrix implantates | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 8 | |
dc.relation.ispartofseries-volume | 32 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1056 | |
dc.source.id | SCOPUS03404285-2007-32-8-SID34748862992 |