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dc.contributor.author | Safin D. | |
dc.contributor.author | Sokolov F. | |
dc.contributor.author | Szyrwiel Ł. | |
dc.contributor.author | Babashkina M. | |
dc.contributor.author | Gimadiev T. | |
dc.contributor.author | Hahn F. | |
dc.contributor.author | Kozlowski H. | |
dc.contributor.author | Krivolapov D. | |
dc.contributor.author | Litvinov I. | |
dc.date.accessioned | 2018-09-18T20:07:49Z | |
dc.date.available | 2018-09-18T20:07:49Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/136801 | |
dc.description.abstract | The reaction of the potassium salts of N-(thio)phosphorylated thioureas of the common formula AdN(H)C(S)N(H)P(X)(OiPr)2 (X = O, HLI; X = S, HLII) with the Ni(II) cation in aqueous EtOH leads to [Ni(LI,II)2] chelate complexes. The molecular structures of the thioureas HLI,II and the complexes [Ni(LI-N,S)2] and [Ni(LII-S,S′)2] were elucidated by single crystal X-ray diffraction analysis, IR, 1H and 31P NMR spectroscopy and microanalysis. In the complex [Ni(LI)2], the metal center is found to be in a square-planar N2S2 environment formed by the C{double bond, long}S sulfur atoms and the P-N nitrogen atoms of two deprotonated LI ligands. The ligands are in a trans configuration. The Ni(II) atom in complex [Ni(LII)2], with the deprotonated thiourea LII, is coordinated in a square-planar fashion by the C{double bond, long}S and P{double bond, long}S sulfur atoms of two anionic ligands. The ligands are in a cis configuration. © 2008 Elsevier Ltd. All rights reserved. | |
dc.relation.ispartofseries | Polyhedron | |
dc.subject | Chelate | |
dc.subject | Crystal structures | |
dc.subject | Hydrogen bond | |
dc.subject | N-(Thio)phosphorylthiourea | |
dc.subject | Nickel complexes | |
dc.title | Nickel(II) complexes with N-(thio)phosphorylthioureas AdNHC(S)NHP(X)(OiPr)2: Versatile coordination of phosphoryl (X = O) and thiophosphoryl (X = S) derivatives | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 11 | |
dc.relation.ispartofseries-volume | 27 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 2271 | |
dc.source.id | SCOPUS02775387-2008-27-11-SID47049089267 |