dc.contributor.author |
Safin D. |
|
dc.contributor.author |
Sokolov F. |
|
dc.contributor.author |
Szyrwiel Ł. |
|
dc.contributor.author |
Babashkina M. |
|
dc.contributor.author |
Gimadiev T. |
|
dc.contributor.author |
Hahn F. |
|
dc.contributor.author |
Kozlowski H. |
|
dc.contributor.author |
Krivolapov D. |
|
dc.contributor.author |
Litvinov I. |
|
dc.date.accessioned |
2018-09-18T20:07:49Z |
|
dc.date.available |
2018-09-18T20:07:49Z |
|
dc.date.issued |
2008 |
|
dc.identifier.issn |
0277-5387 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/136801 |
|
dc.description.abstract |
The reaction of the potassium salts of N-(thio)phosphorylated thioureas of the common formula AdN(H)C(S)N(H)P(X)(OiPr)2 (X = O, HLI; X = S, HLII) with the Ni(II) cation in aqueous EtOH leads to [Ni(LI,II)2] chelate complexes. The molecular structures of the thioureas HLI,II and the complexes [Ni(LI-N,S)2] and [Ni(LII-S,S′)2] were elucidated by single crystal X-ray diffraction analysis, IR, 1H and 31P NMR spectroscopy and microanalysis. In the complex [Ni(LI)2], the metal center is found to be in a square-planar N2S2 environment formed by the C{double bond, long}S sulfur atoms and the P-N nitrogen atoms of two deprotonated LI ligands. The ligands are in a trans configuration. The Ni(II) atom in complex [Ni(LII)2], with the deprotonated thiourea LII, is coordinated in a square-planar fashion by the C{double bond, long}S and P{double bond, long}S sulfur atoms of two anionic ligands. The ligands are in a cis configuration. © 2008 Elsevier Ltd. All rights reserved. |
|
dc.relation.ispartofseries |
Polyhedron |
|
dc.subject |
Chelate |
|
dc.subject |
Crystal structures |
|
dc.subject |
Hydrogen bond |
|
dc.subject |
N-(Thio)phosphorylthiourea |
|
dc.subject |
Nickel complexes |
|
dc.title |
Nickel(II) complexes with N-(thio)phosphorylthioureas AdNHC(S)NHP(X)(OiPr)2: Versatile coordination of phosphoryl (X = O) and thiophosphoryl (X = S) derivatives |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
11 |
|
dc.relation.ispartofseries-volume |
27 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2271 |
|
dc.source.id |
SCOPUS02775387-2008-27-11-SID47049089267 |
|