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A "sodium trap" based on benzo-15-crown-5 with an exocyclic N-(thiophosphoryl)thiourea moiety

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dc.contributor.author Sokolov F.
dc.contributor.author Safin D.
dc.contributor.author Babashkina M.
dc.contributor.author Zabirov N.
dc.contributor.author Brusko V.
dc.contributor.author Mironov N.
dc.contributor.author Krivolapov D.
dc.contributor.author Litvinov I.
dc.contributor.author Cherkasov R.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-18T20:07:49Z
dc.date.available 2018-09-18T20:07:49Z
dc.date.issued 2007
dc.identifier.issn 0277-5387
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/136800
dc.description.abstract For N-(thio)phosphorylthioureas of the common formula RC(S)NHP(X)(OiPr)2 HLI (R = N-(4′-aminobenzo-15-crown-5), X = S), HLII (R = N-(4′-aminobenzo-15-crown-5), X = O), HLIII (R = PhNH, X = S), HLIV (R = PhNH, X = O), and (N,N′-bis-[C(S)NHP(S)(OiPr)2]2-1,10-diaza-18-crown-6) H2LV, salts LiLI,III,IV, NaLI-IV, KLI-IV M2LV (M = Li+, Na+, K+), Ba(LI,III,IV)2, and BaLV have been synthesized and investigated. Compounds NaLI,II quantitatively drop out as a deposit in ethanol medium, allowing the separation of Na+ and K+ cations. This effect is not displayed for the other compounds. The crystal structures of HLIII and the solvate of the composition [K(Me2CO)LIII] have been investigated by X-ray crystallography. © 2006 Elsevier Ltd. All rights reserved.
dc.relation.ispartofseries Polyhedron
dc.subject Chelates
dc.subject Coordination modes
dc.subject Crown-ethers
dc.subject Crystal structures
dc.subject N-thioacylamido(thio)phosphates
dc.title A "sodium trap" based on benzo-15-crown-5 with an exocyclic N-(thiophosphoryl)thiourea moiety
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 26
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1550
dc.source.id SCOPUS02775387-2007-26-7-SID34147141403

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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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