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dc.contributor.author | Sokolov F. | |
dc.contributor.author | Safin D. | |
dc.contributor.author | Zabirov N. | |
dc.contributor.author | Verat A. | |
dc.contributor.author | Brusko V. | |
dc.contributor.author | Krivolapov D. | |
dc.contributor.author | Mironova E. | |
dc.contributor.author | Litvinov I. | |
dc.date.accessioned | 2018-09-18T20:07:48Z | |
dc.date.available | 2018-09-18T20:07:48Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/136797 | |
dc.description.abstract | The reaction of bis-thiourea o-C6H4[NHC(S)NHP(S)(Oi-Pr)2]2 (1) with iodine, KOH and ClCH2C(O)OCH3 leads to O,O′-diisopropyl-1,3-dihydro-2H-benzimidazol-2-ylideneamidothiophosphate (2) formation. The complex of the potassium salt of compound 2 with 18-crown-6, having the composition [K(18-crown-6)L], has been synthesized. Bis-thiourea [CH2NHC(S)NHP(S)(Oi-Pr)2]2 (6) forms a stable potassium salt, which oxidation by iodine leads to a product of heterocyclization, O,O′-diisopropyl-(1-{[(diisopropoxyphosphorothio)amino]carbonothioyl}imidazolidine-2-ylidene)amidothiophosphate (8), in which one of the thiourea fragments is kept. © 2006 Elsevier Ltd. All rights reserved. | |
dc.relation.ispartofseries | Polyhedron | |
dc.subject | Crown-ether | |
dc.subject | Crystal structures | |
dc.subject | Heterocycles | |
dc.subject | Phosphorylated derivatives | |
dc.subject | Thioureas | |
dc.title | Synthesis, structure and properties of novel N-thiophosphorylated derivatives of 1,3-dihydro-2H-benzimidazol-2-imine and imidazolidine-2-imine | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 18 | |
dc.relation.ispartofseries-volume | 25 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 3611 | |
dc.source.id | SCOPUS02775387-2006-25-18-SID37849186117 |