dc.contributor.author |
Khrizanforova V. |
|
dc.contributor.author |
Musina E. |
|
dc.contributor.author |
Khrizanforov M. |
|
dc.contributor.author |
Gerasimova T. |
|
dc.contributor.author |
Katsyuba S. |
|
dc.contributor.author |
Spiridonova Y. |
|
dc.contributor.author |
Islamov D. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Karasik A. |
|
dc.contributor.author |
Sinyashin O. |
|
dc.contributor.author |
Budnikova Y. |
|
dc.date.accessioned |
2018-09-18T20:05:30Z |
|
dc.date.available |
2018-09-18T20:05:30Z |
|
dc.date.issued |
2015 |
|
dc.identifier.issn |
0022-328X |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/136423 |
|
dc.description.abstract |
© 2015 Elsevier B.V. All rights reserved. The two new nickel complexes [Ni(P<sup>R</sup><inf>2</inf>N<sup>Ph(CH)Ph</sup><inf>2</inf>)<inf>2</inf>]<sup>2+</sup> (where R = Ph or o-Py) with cyclic 1,5-diaza-3,7-diphosphacyclooctane ligands have been synthesized. All complexes are effective electrocatalysts for hydrogen production using [(DMF)H]<sup>+</sup> as proton source in acetonitrile. The bulky benzhydryl substituent at nitrogen atom leads to higher catalytic activity comparison to benzyl. The introduction o-Py substituents at phosphorus as additional basic center is caused by the changing of voltage-current picture and significantly catalytic current enhancement. TOFs being 100 and 15200 s<sup>-1</sup> for R = Ph and o-Py, respectively. |
|
dc.relation.ispartofseries |
Journal of Organometallic Chemistry |
|
dc.subject |
1,5-Diaza-3,7-diphosphacyclooctanes |
|
dc.subject |
Catalysis hydrogen economy |
|
dc.subject |
Electrochemistry |
|
dc.subject |
Nickel |
|
dc.subject |
Pyridylbisphosphines |
|
dc.title |
Unexpected ligand effect on the catalytic reaction rate acceleration for hydrogen production using biomimetic nickel electrocatalysts with 1,5-diaza-3,7-diphosphacyclooctanes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-volume |
789-790 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
14 |
|
dc.source.id |
SCOPUS0022328X-2015-789-790-SID84929313201 |
|