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Synthesis, structure and electrochemical properties of the organonickel complex [NiBr(Mes)(phen)] (Mes = 2,4,6-trimethylphenyl, phen = 1,10-phenanthroline)

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dc.contributor.author Yakhvarov D.
dc.contributor.author Petr A.
dc.contributor.author Kataev V.
dc.contributor.author Büchner B.
dc.contributor.author Gómez-Ruiz S.
dc.contributor.author Hey-Hawkins E.
dc.contributor.author Kvashennikova S.
dc.contributor.author Ganushevich Y.
dc.contributor.author Morozov V.
dc.contributor.author Sinyashin O.
dc.date.accessioned 2018-09-18T20:05:29Z
dc.date.available 2018-09-18T20:05:29Z
dc.date.issued 2014
dc.identifier.issn 0022-328X
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/136420
dc.description.abstract The organonickel complex [NiBr(Mes)(phen)] (1) (Mes = 2,4,6- trimethylphenyl, phen = 1,10-phenanthroline) was synthesized by oxidative addition of MesBr to nickel(0) complexes, obtained from [Ni(COD)2] (COD = 1,5-cyclooctadiene) and phen, or electrochemically generated from [NiBr2(phen)], and by ligand exchange reaction from [NiBr(Mes)(PPh3)2]. The electrochemical properties of [NiBr(Mes)(phen)] were investigated by cyclic voltammetry and in situ EPR spectroelectrochemistry. The cathodic reduction of 1 resulted in formation of the neutral radical complex [Ni(Mes)(phen-)] with a 1,10-phenanthroline radical anion bound to a nickel(II) centre. The electrochemical generation of the free 1,10-phenanthroline radical anion from 1,10-phenanthroline is also described. © 2013 Elsevier B.V. All rights reserved.
dc.relation.ispartofseries Journal of Organometallic Chemistry
dc.subject 1,10-Phenanthroline
dc.subject Electrochemistry
dc.subject Electroreduction
dc.subject In situ EPR spectroelectrochemistry
dc.subject Ligand dissociation
dc.subject Organonickel σ-complexes
dc.title Synthesis, structure and electrochemical properties of the organonickel complex [NiBr(Mes)(phen)] (Mes = 2,4,6-trimethylphenyl, phen = 1,10-phenanthroline)
dc.type Article
dc.relation.ispartofseries-volume 750
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 59
dc.source.id SCOPUS0022328X-2014-750-SID84888381345


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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