Hydrogen bonds in self- and heteroassociates of cumyl hydroperoxide in solutions and polymeric matrixes

dc.contributor.author	Kamalova D.
dc.contributor.author	Kolyadko I.
dc.contributor.author	Remizov A.
dc.contributor.author	Semenov M.
dc.contributor.author	Skochilov R.
dc.date.accessioned	2018-09-18T20:05:17Z
dc.date.available	2018-09-18T20:05:17Z
dc.date.issued	2010
dc.identifier.issn	0022-2860
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/136383
dc.description.abstract	Self- and heteroassociation of cumyl hydroperoxide hydrogen bonded with acetone, acetophenone and acetonitrile as a proton acceptor in n-decane solutions was studied by FTIR spectroscopy in the range of 3100-3700 cm-1. The hydrogen bonds of cumyl hydroperoxide were investigated in both benzene and two polymeric matrixes. To interpret spectroscopic data the factor analysis was used. Equilibrium constants and thermodynamic parameters of the heteroassociate formation were determined. The DFT calculations of self- and heteroassociates of cumyl hydroperoxide were carried out. © 2010 Elsevier B.V. All rights reserved.
dc.relation.ispartofseries	Journal of Molecular Structure
dc.subject	Conformation
dc.subject	DFT calculation
dc.subject	Factor analysis
dc.subject	Hydrogen bond
dc.subject	Infrared spectra
dc.title	Hydrogen bonds in self- and heteroassociates of cumyl hydroperoxide in solutions and polymeric matrixes
dc.type	Article
dc.relation.ispartofseries-issue	1-3
dc.relation.ispartofseries-volume	972
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	104
dc.source.id	SCOPUS00222860-2010-972-13-SID77952103183

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.