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Thermochemistry of uracil and thymine revisited

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dc.contributor.author Emel'Yanenko V.
dc.contributor.author Verevkin S.
dc.contributor.author Notario R.
dc.date.accessioned 2018-09-18T20:04:57Z
dc.date.available 2018-09-18T20:04:57Z
dc.date.issued 2015
dc.identifier.issn 0021-9614
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/136329
dc.description.abstract © 2015 Published by Elsevier Ltd. Thermochemical properties of uracil and thymine have been evaluated using additional experiments. Standard (p<sup>0</sup> = 0.1 MPa) molar enthalpies of formation in the gas phase at T = 298.15 K for uracil -(298.1 ± 0.6) and for thymine -(337.6 ± 0.9) kJ · mol<sup>-1</sup> have been derived from energies of combustion measured by static bomb combustion calorimetry and molar enthalpies of sublimation determined using the transpiration method. The G3 and G4 quantum-chemical methods were used for calculations of theoretical gaseous enthalpies of formation being in very good agreement with the re-measured experimental values.
dc.relation.ispartofseries Journal of Chemical Thermodynamics
dc.subject Enthalpy of formation
dc.subject Enthalpy of sublimation
dc.subject Quantum chemical calculation
dc.subject Thermochemistry
dc.subject Thymine
dc.subject Uracil
dc.subject Vapour pressure
dc.title Thermochemistry of uracil and thymine revisited
dc.type Article
dc.relation.ispartofseries-volume 87
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 129
dc.source.id SCOPUS00219614-2015-87-SID84927759837


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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