Thermochemistry of uracil and thymine revisited

dc.contributor.author	Emel'Yanenko V.
dc.contributor.author	Verevkin S.
dc.contributor.author	Notario R.
dc.date.accessioned	2018-09-18T20:04:57Z
dc.date.available	2018-09-18T20:04:57Z
dc.date.issued	2015
dc.identifier.issn	0021-9614
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/136329
dc.description.abstract	© 2015 Published by Elsevier Ltd. Thermochemical properties of uracil and thymine have been evaluated using additional experiments. Standard (p<sup>0</sup> = 0.1 MPa) molar enthalpies of formation in the gas phase at T = 298.15 K for uracil -(298.1 ± 0.6) and for thymine -(337.6 ± 0.9) kJ · mol<sup>-1</sup> have been derived from energies of combustion measured by static bomb combustion calorimetry and molar enthalpies of sublimation determined using the transpiration method. The G3 and G4 quantum-chemical methods were used for calculations of theoretical gaseous enthalpies of formation being in very good agreement with the re-measured experimental values.
dc.relation.ispartofseries	Journal of Chemical Thermodynamics
dc.subject	Enthalpy of formation
dc.subject	Enthalpy of sublimation
dc.subject	Quantum chemical calculation
dc.subject	Thermochemistry
dc.subject	Thymine
dc.subject	Uracil
dc.subject	Vapour pressure
dc.title	Thermochemistry of uracil and thymine revisited
dc.type	Article
dc.relation.ispartofseries-volume	87
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	129
dc.source.id	SCOPUS00219614-2015-87-SID84927759837

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.