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dc.contributor.author | Safin D. | |
dc.contributor.author | Babashkina M. | |
dc.contributor.author | Bolte M. | |
dc.contributor.author | Sokolov F. | |
dc.contributor.author | Brusko V. | |
dc.date.accessioned | 2018-09-18T20:03:57Z | |
dc.date.available | 2018-09-18T20:03:57Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/136163 | |
dc.description.abstract | Reaction of the potassium salts of N-thiophosphorylated thioureas of common formula RNHC(S)NHP(S)(OiPr)2 [R = pyridin-2-yl (HLa), pyridin-3-yl (HLb), 6-amino-pyridin-2-yl (HLc)] with Cu(PPh3)3I in aqueous EtOH/CH2Cl2 leads to mononuclear [Cu(PPh3)2La,b-S,S′] (1, 2) and [Cu(PPh3)Lc-S,S′] (3) complexes. Using copper(I) iodide instead of Cu(PPh3)3I, polynuclear complexes [Cun(L-S,S′)n] (4-6) were obtained. The structures of these compounds were investigated by IR, 1H, 31P{1H} NMR spectroscopy, ES-MS and elemental analyses. The crystal structures of Cu(PPh3)2Lb (2) and Cu(PPh3)Lc (3) were determined by single-crystal X-ray diffraction. © 2008 Elsevier B.V. All rights reserved. | |
dc.relation.ispartofseries | Inorganica Chimica Acta | |
dc.subject | Chelate | |
dc.subject | Copper | |
dc.subject | Crystal structures | |
dc.subject | N-Thiophosphorylthiourea | |
dc.subject | Triphenylphosphine | |
dc.title | Complexes of N-thiophosphorylthioureas RNHC(S)NHP(S)(OiPr)2 (HL) (R = pyridin-2-yl, pyridin-3-yl, 6-amino-pyridin-2-yl) with copper(I): Crystal structures of Cu(PPh3)nL (n = 1, 2) | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 6 | |
dc.relation.ispartofseries-volume | 362 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1895 | |
dc.source.id | SCOPUS00201693-2009-362-6-SID64449088556 |