dc.contributor.author |
Safin D. |
|
dc.contributor.author |
Babashkina M. |
|
dc.contributor.author |
Bolte M. |
|
dc.contributor.author |
Sokolov F. |
|
dc.contributor.author |
Brusko V. |
|
dc.date.accessioned |
2018-09-18T20:03:57Z |
|
dc.date.available |
2018-09-18T20:03:57Z |
|
dc.date.issued |
2009 |
|
dc.identifier.issn |
0020-1693 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/136163 |
|
dc.description.abstract |
Reaction of the potassium salts of N-thiophosphorylated thioureas of common formula RNHC(S)NHP(S)(OiPr)2 [R = pyridin-2-yl (HLa), pyridin-3-yl (HLb), 6-amino-pyridin-2-yl (HLc)] with Cu(PPh3)3I in aqueous EtOH/CH2Cl2 leads to mononuclear [Cu(PPh3)2La,b-S,S′] (1, 2) and [Cu(PPh3)Lc-S,S′] (3) complexes. Using copper(I) iodide instead of Cu(PPh3)3I, polynuclear complexes [Cun(L-S,S′)n] (4-6) were obtained. The structures of these compounds were investigated by IR, 1H, 31P{1H} NMR spectroscopy, ES-MS and elemental analyses. The crystal structures of Cu(PPh3)2Lb (2) and Cu(PPh3)Lc (3) were determined by single-crystal X-ray diffraction. © 2008 Elsevier B.V. All rights reserved. |
|
dc.relation.ispartofseries |
Inorganica Chimica Acta |
|
dc.subject |
Chelate |
|
dc.subject |
Copper |
|
dc.subject |
Crystal structures |
|
dc.subject |
N-Thiophosphorylthiourea |
|
dc.subject |
Triphenylphosphine |
|
dc.title |
Complexes of N-thiophosphorylthioureas RNHC(S)NHP(S)(OiPr)2 (HL) (R = pyridin-2-yl, pyridin-3-yl, 6-amino-pyridin-2-yl) with copper(I): Crystal structures of Cu(PPh3)nL (n = 1, 2) |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
6 |
|
dc.relation.ispartofseries-volume |
362 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1895 |
|
dc.source.id |
SCOPUS00201693-2009-362-6-SID64449088556 |
|