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Coordination diversity of N-phosphoryl-N′-phenylthiourea (LH) towards CoII, NiII and PdII cations: Crystal structure of ML2-N,S and ML2-O,S chelates

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dc.contributor.author Sokolov F.
dc.contributor.author Zabirov N.
dc.contributor.author Yamalieva L.
dc.contributor.author Shtyrlin V.
dc.contributor.author Garipov R.
dc.contributor.author Brusko V.
dc.contributor.author Verat A.
dc.contributor.author Baranov S.
dc.contributor.author Mlynarz P.
dc.contributor.author Glowiak T.
dc.contributor.author Kozlowski H.
dc.date.accessioned 2018-09-18T20:03:56Z
dc.date.available 2018-09-18T20:03:56Z
dc.date.issued 2006
dc.identifier.issn 0020-1693
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/136162
dc.description.abstract Thiourea, PhNHC(S)NHP(O)(OPri)2 (LH) chelates of CoII, NiII, and PdII ions have been obtained and investigated by single-crystal X-ray diffraction, UV, IR, NMR spectroscopy, and EI mass-spectrometry. The unusual 1,3-N,S-coordination via sulfur and NP(O) nitrogen atoms has been found in the trans-square-planar NiL2 and PdL2 complexes, whereas the 1,5-O,S-coordination is realized in the tetrahedral CoL2 complex. DFT calculations have revealed significant stabilization of the 1,3-N,S-structures due to stronger crystal field and the NH-O{double bond, long}P hydrogen bonds. © 2006 Elsevier B.V. All rights reserved.
dc.relation.ispartofseries Inorganica Chimica Acta
dc.subject CoII complexes
dc.subject N,S-coordination
dc.subject NiII complexes
dc.subject O,S-coordination
dc.subject PdII complexes
dc.subject Substituent effects
dc.subject Thiourea coordination
dc.title Coordination diversity of N-phosphoryl-N′-phenylthiourea (LH) towards CoII, NiII and PdII cations: Crystal structure of ML2-N,S and ML2-O,S chelates
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 359
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 2087
dc.source.id SCOPUS00201693-2006-359-7-SID33645851650


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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