Redox-induced change in the ligand coordination mode

dc.contributor.author	Ovcharenko V.
dc.contributor.author	Kuznetsova O.
dc.contributor.author	Fursova E.
dc.contributor.author	Romanenko G.
dc.contributor.author	Polushkin A.
dc.contributor.author	Sagdeev R.
dc.date.accessioned	2018-09-18T20:03:53Z
dc.date.available	2018-09-18T20:03:53Z
dc.date.issued	2014
dc.identifier.issn	0020-1669
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/136154
dc.description.abstract	© 2014 American Chemical Society. The reaction of cobalt(II) pivalate with a spin-labeled Schiff base (HL1) in organic solvents formed trinuclear complex [Co3(Piv)2L1 2L2 2]·Solv (Solv is Me2CO and/or C7H16 and CH3CN) containing both nitroxide L1 and the product of its single-electron reduction, nitrone L2. The formation of [Co3(Piv)2L1 2L2 2] was a consequence of an unusual phenomenon, which we called "redox-induced change in the ligand coordination mode". A reduction of L1 to L2 led to a change in the set of donor atoms and even in the size of the metallocycle. This phenomenon was also found for mononuclear [CrL1 2L2] and [FeL1 2L2]·Me2CO.
dc.relation.ispartofseries	Inorganic Chemistry
dc.title	Redox-induced change in the ligand coordination mode
dc.type	Article
dc.relation.ispartofseries-issue	19
dc.relation.ispartofseries-volume	53
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	10033
dc.source.id	SCOPUS00201669-2014-53-19-SID84907831086

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