Pressure effect on the rate and equilibrium constants of the Diels- Alder reaction 9-chloroanthracene with tetracyanoethylene

dc.contributor.author	Kiselev V.
dc.contributor.author	Kashaeva E.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-17T21:50:10Z
dc.date.available	2018-09-17T21:50:10Z
dc.date.issued	1999
dc.identifier.issn	0040-4020
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/135496
dc.description.abstract	The pressure effect on the forward and backward rate constants and equilibrium constants of the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene has been investigated in 1,2-dichloroethane up to 1000 kgcm-2 at 298.15 K. The reaction volume obtained from the pressure effect on equilibrium (-20.6 ±1.5 cm3 mol-1) and as difference of activation volumes of forward (-28.5±1.5) and backward (-6.5 ± 0.5) reaction (- 22.0±1.5 cm3 mol-1) are in agreement with partial molar volume difference of adduct (255.5±1.5) {diene (170.7±0.5) and dienophile (107.8±0.2)} giving -23.0 ±2 cm3 mol-1.
dc.relation.ispartofseries	Tetrahedron
dc.title	Pressure effect on the rate and equilibrium constants of the Diels- Alder reaction 9-chloroanthracene with tetracyanoethylene
dc.type	Article
dc.relation.ispartofseries-issue	4
dc.relation.ispartofseries-volume	55
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1153
dc.source.id	SCOPUS00404020-1999-55-4-SID0033593360

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.