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dc.contributor.author | Klimovitskiǐ A. | |
dc.contributor.author | Remizov A. | |
dc.contributor.author | Skvortsov A. | |
dc.contributor.author | Fishman A. | |
dc.date.accessioned | 2018-09-17T21:46:54Z | |
dc.date.available | 2018-09-17T21:46:54Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 0036-0244 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/135427 | |
dc.description.abstract | The IR spectra and the exo ⇄ endo conformational equilibrium of 1,9,10,11,12,12-hexachloro-4,6-dioxatricyclo[9,2,1,02,8]dodeca-10- ene (HCA) in carbon disulfide were studied in the temperature range 230-300 K. The difference of the enthalpies was found to be 2.7(2) kJ/mol in favor of the exo conformer. The kinetics of the conformational transition of HCA in acetone-d6 and carbon disulphide was studied in the temperature range 213-220 K. The enthalpies ΔH≠exo and entropies ΔS≠exo of activation of the exo → endo conformational transition were found to be ΔH≠exo = 51(4) and 70(2) kJ/mol and ΔS≠exo = -76(20) and -11(7) J/(mol K) in acetone-d 6 and carbon disulphide, respectively. The ratios between the absorption coefficients of the endo and exo conformer bands (727 cm -1 and 786 cm-1, respectively) were found to be 0.63(9) in acetone-d6 and 0.65(5) in carbon disulfide. The differences of the entropies of the HCA conformers in these solvents [ΔS° = -5(2) J/(mol K)] were determined. The absorption bands were assigned based on the results of quantum-chemical ab initio calculations. | |
dc.relation.ispartofseries | Russian Journal of Physical Chemistry A | |
dc.title | An IR spectroscopic study of the kinetics of conformational transitions of 1,9,10,11,12,12-hexachloro-4,6-dioxatricyclo[9,2,1,02,8]dodeca-10- ene in solutions | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 2 | |
dc.relation.ispartofseries-volume | 78 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 249 | |
dc.source.id | SCOPUS00360244-2004-78-2-SID1642398951 |