Composition, Properties, and Structure of Copper(II) Complexes with 2,4-Dihydroxybenzoic Acid

dc.contributor.author	Ginzburg V.
dc.contributor.author	Bulkina E.
dc.contributor.author	Glebov A.
dc.date.accessioned	2018-09-17T21:45:21Z
dc.date.available	2018-09-17T21:45:21Z
dc.date.issued	1998
dc.identifier.issn	0036-0236
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/135391
dc.description.abstract	pH titration, optical spectroscopy, and simulations were used to determine the concentration acidic dissociation constants for 2,4-dihydroxybenzoic acid (H3L) and the compositions, stabilities, and species distribution of copper(II) complexes with H3L. At acidic and neutral pHs, 1 : 1 complexes are dominant. At alkaline pHs, differently protonated 1 : 1, 1 : 2, or 1 : 3 complexes form (including hydroxo complexes [CuLOH]2-, [CuL(OH)2]3-, and [CuL2(OH)2]6-), the formation of the particular species being dependent on the metal-to-ligand ratio.
dc.relation.ispartofseries	Russian Journal of Inorganic Chemistry
dc.title	Composition, Properties, and Structure of Copper(II) Complexes with 2,4-Dihydroxybenzoic Acid
dc.type	Article
dc.relation.ispartofseries-issue	11
dc.relation.ispartofseries-volume	43
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1706
dc.source.id	SCOPUS00360236-1998-43-11-SID2542613023

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