Thiocyanatomolybdenum(V) Complexes

dc.contributor.author	Chichirova N.
dc.contributor.author	Zabbarova R.
dc.contributor.author	Sal'nikov Y.
dc.date.accessioned	2018-09-17T21:45:01Z
dc.date.available	2018-09-17T21:45:01Z
dc.date.issued	1996
dc.identifier.issn	0036-0236
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/135383
dc.description.abstract	Formation of thiocyanatomolybdenum(V) complex ions [MoO(NCS)2]+, H3[MoOCl3(NCS)2]+, H4[MoOCl4(NCS)]2+, H4[MoOCl5]2+, H4[MoOCl3(NCS)]3+, and H2[MoOCl2]3+ (within the range of 0.7-5 mol/l HCl) and H4[MoOBr3(NCS)2]2+ and H4[MoOBr5]2+ (for 5 mol/l HBr) in aqueous solution was shown by means of spectrophotometry and mathematical simulation. As compared to bromide ions, Cl- ions demonstrate a higher competitive ability when thiocyanato ions occur in the coordination sphere of molybdenum(V). The absence of polymeric complex species confirms the depolymerizing properties of the ligand under investigation.
dc.relation.ispartofseries	Russian Journal of Inorganic Chemistry
dc.title	Thiocyanatomolybdenum(V) Complexes
dc.type	Article
dc.relation.ispartofseries-issue	10
dc.relation.ispartofseries-volume	41
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1588
dc.source.id	SCOPUS00360236-1996-41-10-SID2742571788

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.