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The concept of electronegativity. the current state of the problem

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dc.contributor.author Cherkasov A.
dc.contributor.author Galkin V.
dc.contributor.author Zueva E.
dc.contributor.author Cherkasov R.
dc.date.accessioned 2018-09-17T21:44:50Z
dc.date.available 2018-09-17T21:44:50Z
dc.date.issued 1998
dc.identifier.issn 0036-021X
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/135379
dc.description.abstract A systematic account is given of the current ideas about atomic and group electronegativities and the trends in the development of the concept of electroncgativity are analysed. Attention is concentrated on the latest approaches to the definition of electronegativity - the concept of 'orbital' electronegativities and the density functional theory. A procedure is proposed for the determination of 'inductive' electronegativities, which permits a correct theoretical calculation of the electronegativity of a substituent from the electronegativities of individual atoms and the steric structure. It is shown that the approach developed has a series of important advantages - for example, it makes it possible to calculate the group electronegativities of isomeric substituents avoiding the principle of the equalisation of electronegativities. A survey of literature data and generalisation of the method proposed by the authors have made it possible to formulate the concept of electronegativity as an unchanging fundamental immanent characteristic of a chemical element. © 1998 Russian Academy of Sciences and Turpion Ltd.
dc.relation.ispartofseries Russian Chemical Reviews
dc.title The concept of electronegativity. the current state of the problem
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 67
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 375
dc.source.id SCOPUS0036021X-1998-67-5-SID0011109732


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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