dc.contributor.author |
Gorbatchuk V. |
|
dc.contributor.author |
Mironov N. |
|
dc.contributor.author |
Solomonov B. |
|
dc.contributor.author |
Habicher W. |
|
dc.date.accessioned |
2018-09-17T21:34:03Z |
|
dc.date.available |
2018-09-17T21:34:03Z |
|
dc.date.issued |
2004 |
|
dc.identifier.issn |
1525-7797 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/135159 |
|
dc.description.abstract |
Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K The hydration above 0.09-0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good norhydroxylic sorbate acetonitrile. © 2004 American Chemical Society. |
|
dc.relation.ispartofseries |
Biomacromolecules |
|
dc.title |
Biomimetic cooperative interactions of dried cross-linked poly(N-6-aminohexylacrylamide) with binary mixtures of solvent vapors |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
4 |
|
dc.relation.ispartofseries-volume |
5 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1615 |
|
dc.source.id |
SCOPUS15257797-2004-5-4-SID4143149662 |
|