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dc.contributor.author | Gorbatchuk V. | |
dc.contributor.author | Mironov N. | |
dc.contributor.author | Solomonov B. | |
dc.contributor.author | Habicher W. | |
dc.date.accessioned | 2018-09-17T21:34:03Z | |
dc.date.available | 2018-09-17T21:34:03Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1525-7797 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/135159 | |
dc.description.abstract | Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K The hydration above 0.09-0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good norhydroxylic sorbate acetonitrile. © 2004 American Chemical Society. | |
dc.relation.ispartofseries | Biomacromolecules | |
dc.title | Biomimetic cooperative interactions of dried cross-linked poly(N-6-aminohexylacrylamide) with binary mixtures of solvent vapors | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 4 | |
dc.relation.ispartofseries-volume | 5 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1615 | |
dc.source.id | SCOPUS15257797-2004-5-4-SID4143149662 |