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dc.contributor.author | Crespo O. | |
dc.contributor.author | Brusko V. | |
dc.contributor.author | Gimeno M. | |
dc.contributor.author | Tornil M. | |
dc.contributor.author | Laguna A. | |
dc.contributor.author | Zabirov N. | |
dc.date.accessioned | 2018-09-17T21:33:11Z | |
dc.date.available | 2018-09-17T21:33:11Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1434-1948 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/135140 | |
dc.description.abstract | Gold and silver complexes with the N-[bis(isopropoxy)-thiophosphoryl]thiobenzamide (HL1) and N-[bis(isopropoxy)-thiophosphoryl]-N′-phenylthiourea (HL2) ligands are reported, The compounds [M(HL)(PPh3)]TfO, [Ag(HL)(TfO)] and [Ag(HL)(PPh3)2]TfO were obtained by the reaction of both ligands with the corresponding trifluoromethanesulfonate salts. The (acetylacetonato)gold and -silver materials [M(acac)(PPh3)] or [Au(acac)(C6F5)2] cause deprotonation of the ligands and afford [ML(PPh3)] or [AuL(C6F 5)2], whereas the reaction of [Au(TfO)(PPh3)] with HL1 in a 2:1 molar ratio in KOH/MeOH affords [Au 2(L1)(PPh3)2]TfO, The first homoleptic anionic metal compounds [AuIL2]- are also reported. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004. | |
dc.relation.ispartofseries | European Journal of Inorganic Chemistry | |
dc.subject | Gold | |
dc.subject | Silver | |
dc.subject | Sulfur | |
dc.subject | Thioamide | |
dc.subject | Thiourea | |
dc.title | Gold and Silver Complexes with the Ligands N-[Bis(isopropoxy)-thiophosphoryl]thiobenzamide and N-[Bis(isopropoxy)thiophosphoryl]-N′-phenylthiourea | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 2 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 423 | |
dc.source.id | SCOPUS14341948-2004-2-SID0742288605 |