dc.contributor.author |
Crespo O. |
|
dc.contributor.author |
Brusko V. |
|
dc.contributor.author |
Gimeno M. |
|
dc.contributor.author |
Tornil M. |
|
dc.contributor.author |
Laguna A. |
|
dc.contributor.author |
Zabirov N. |
|
dc.date.accessioned |
2018-09-17T21:33:11Z |
|
dc.date.available |
2018-09-17T21:33:11Z |
|
dc.date.issued |
2004 |
|
dc.identifier.issn |
1434-1948 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/135140 |
|
dc.description.abstract |
Gold and silver complexes with the N-[bis(isopropoxy)-thiophosphoryl]thiobenzamide (HL1) and N-[bis(isopropoxy)-thiophosphoryl]-N′-phenylthiourea (HL2) ligands are reported, The compounds [M(HL)(PPh3)]TfO, [Ag(HL)(TfO)] and [Ag(HL)(PPh3)2]TfO were obtained by the reaction of both ligands with the corresponding trifluoromethanesulfonate salts. The (acetylacetonato)gold and -silver materials [M(acac)(PPh3)] or [Au(acac)(C6F5)2] cause deprotonation of the ligands and afford [ML(PPh3)] or [AuL(C6F 5)2], whereas the reaction of [Au(TfO)(PPh3)] with HL1 in a 2:1 molar ratio in KOH/MeOH affords [Au 2(L1)(PPh3)2]TfO, The first homoleptic anionic metal compounds [AuIL2]- are also reported. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004. |
|
dc.relation.ispartofseries |
European Journal of Inorganic Chemistry |
|
dc.subject |
Gold |
|
dc.subject |
Silver |
|
dc.subject |
Sulfur |
|
dc.subject |
Thioamide |
|
dc.subject |
Thiourea |
|
dc.title |
Gold and Silver Complexes with the Ligands N-[Bis(isopropoxy)-thiophosphoryl]thiobenzamide and N-[Bis(isopropoxy)thiophosphoryl]-N′-phenylthiourea |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
423 |
|
dc.source.id |
SCOPUS14341948-2004-2-SID0742288605 |
|