Kazan Federal University Digital Repository

Synthesis of mesityl oxide π-complexes with metals of chromium subgroup and with iron. Theoretical and experimental investigation of the ligand dissociation energy

Show simple item record

dc.contributor.author Kuramshin A.
dc.contributor.author Kuramshina E.
dc.contributor.author Cherkasov R.
dc.date.accessioned 2018-09-17T21:28:13Z
dc.date.available 2018-09-17T21:28:13Z
dc.date.issued 2005
dc.identifier.issn 1070-4280
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/135038
dc.description.abstract At the use of photochemical and thermochemical activation new π-complexes of chromium, molybdenum, and tungsten were prepared containing in the coordination sphere η2- and η4-molecules of 4-methyl-3-penten-2-one. Nonempirical methods were applied to calculation of the energy parameters of the coordinated molecules, and the factors governing the η2- and η4-coordination of the oxodiene system were established. A thermochemical study was performed on the 4-methyl-3-penten-2-one η4-coordination product with carbonyl metal core. A scheme of the thermal decomposition was suggested for the iron (0) η 4-(4-methyl-3-penten-2-one)tricarbonyl. ©2005 Pleiades Publishing, Inc.
dc.relation.ispartofseries Russian Journal of Organic Chemistry
dc.title Synthesis of mesityl oxide π-complexes with metals of chromium subgroup and with iron. Theoretical and experimental investigation of the ligand dissociation energy
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 41
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 649
dc.source.id SCOPUS10704280-2005-41-5-SID22444444093


Files in this item

This item appears in the following Collection(s)

  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

Show simple item record

Search DSpace


Advanced Search

Browse

My Account

Statistics