Reactivity of One-Coordinate Phosphorus Compounds. Kinetics of Diels-Alder Reactions of Tetraphenylcylopentadienone with Compounds Containing C≡P, C≡C, and C≡N Bonds

dc.contributor.author	Kiselev V.
dc.contributor.author	Patsanovskii I.
dc.contributor.author	Kashaeva E.
dc.contributor.author	Popova E.
dc.contributor.author	Mueller C.
dc.contributor.author	Schmutzler R.
dc.contributor.author	Ishmaeva E.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-17T21:27:03Z
dc.date.available	2018-09-17T21:27:03Z
dc.date.issued	1996
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/135011
dc.description.abstract	The kinetics of the Diels-Alder reactions of tetraphenylcyclopentadiene with tert-butylphosphaethyne, tert-butylacetylene, and butyronitrile have been studied in toluene at 110°C. The rate constants of these reactions, calculated with regard to thermal reduction of tetraphenylcyclopentadiene (rate constant 4.27 x 10-7 s-1), are 2.87 x 10-4, 4.09 x 10-6, and 2.7 x 10-8 1 mol-1 s-1, respectively. The reactions can be classed with those involving diene as acceptor and dienophile as donor.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.title	Reactivity of One-Coordinate Phosphorus Compounds. Kinetics of Diels-Alder Reactions of Tetraphenylcylopentadienone with Compounds Containing C≡P, C≡C, and C≡N Bonds
dc.type	Article
dc.relation.ispartofseries-issue	12
dc.relation.ispartofseries-volume	32
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1795
dc.source.id	SCOPUS10704280-1996-32-12-SID0030311334

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