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Reactivity of One-Coordinate Phosphorus Compounds. Kinetics of Diels-Alder Reactions of Tetraphenylcylopentadienone with Compounds Containing C≡P, C≡C, and C≡N Bonds

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dc.contributor.author Kiselev V.
dc.contributor.author Patsanovskii I.
dc.contributor.author Kashaeva E.
dc.contributor.author Popova E.
dc.contributor.author Mueller C.
dc.contributor.author Schmutzler R.
dc.contributor.author Ishmaeva E.
dc.contributor.author Konovalov A.
dc.date.accessioned 2018-09-17T21:27:03Z
dc.date.available 2018-09-17T21:27:03Z
dc.date.issued 1996
dc.identifier.issn 1070-4280
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/135011
dc.description.abstract The kinetics of the Diels-Alder reactions of tetraphenylcyclopentadiene with tert-butylphosphaethyne, tert-butylacetylene, and butyronitrile have been studied in toluene at 110°C. The rate constants of these reactions, calculated with regard to thermal reduction of tetraphenylcyclopentadiene (rate constant 4.27 x 10-7 s-1), are 2.87 x 10-4, 4.09 x 10-6, and 2.7 x 10-8 1 mol-1 s-1, respectively. The reactions can be classed with those involving diene as acceptor and dienophile as donor.
dc.relation.ispartofseries Russian Journal of Organic Chemistry
dc.title Reactivity of One-Coordinate Phosphorus Compounds. Kinetics of Diels-Alder Reactions of Tetraphenylcylopentadienone with Compounds Containing C≡P, C≡C, and C≡N Bonds
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 32
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1795
dc.source.id SCOPUS10704280-1996-32-12-SID0030311334


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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