Specific features of the structure of chelate complexes of N-thiocarbamoylamidophosphates with Zn(II) and Cd(II) cations

dc.contributor.author	Sokolov F.
dc.contributor.author	Safin D.
dc.contributor.author	Zabirov N.
dc.contributor.author	Zotov P.
dc.contributor.author	Cherkasov R.
dc.date.accessioned	2018-09-17T21:26:06Z
dc.date.available	2018-09-17T21:26:06Z
dc.date.issued	2005
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134988
dc.description.abstract	The reaction of potassium salts of N-thiocarbamoylamidophosphates RC(S)NHP(O)(OPr-i)2X [X = PhNH, p-MeOPhNH, p-BrPhNH, i-PrNH, t-BuNH, Et2N, C5H10N, OC4H8N, C 6H11NH] with Zn(II) cation gives complexes of the composition Zn(L-O,S)2. The Cd(II) complexes could not be isolated under analogous conditions because of their hydrolytic lability. The reaction of thioureas (X = PhNH, p-MeOPhNH) with Cd(II) acetate in DMF provides stable solvato complexes of the composition Cd(DMF)2L2. The structure of the resulting compounds was studied by means of IR, 1H, and 31P NMR spectroscopy and EI and ESI mass spectrometry. © 2005 Pleiades Publishing Inc.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Specific features of the structure of chelate complexes of N-thiocarbamoylamidophosphates with Zn(II) and Cd(II) cations
dc.type	Article
dc.relation.ispartofseries-issue	12
dc.relation.ispartofseries-volume	75
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1919
dc.source.id	SCOPUS10703632-2005-75-12-SID33747830155

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