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Quantum-chemical estimation of the stability and reactivity of diphosphonium salts

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dc.contributor.author Zagumennov V.
dc.contributor.author Vedernikov A.
dc.contributor.author Nikitin E.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-17T21:25:48Z
dc.date.available 2018-09-17T21:25:48Z
dc.date.issued 2003
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/134981
dc.description.abstract For a series of diphosphonium salts containing two positively charged covalently bonded phosphorus atoms, XnY3-nP +P+XnY3-n (X = alkyl substituent, Y = amino group, n = 0-3), the stability, reactivity, and P-P bond strength were evaluated by various physicochemical methods. The P-P bond energy is appreciably influenced by both steric factors and donor properties of the substituents. The calculations confirmed that transformations of diphosphonium salts can involve cleavage of both P-P and P-N (or P-C) bonds.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.title Quantum-chemical estimation of the stability and reactivity of diphosphonium salts
dc.type Article
dc.relation.ispartofseries-issue 6
dc.relation.ispartofseries-volume 73
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 921
dc.source.id SCOPUS10703632-2003-73-6-SID3543008419


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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