dc.contributor.author |
Solomonov B. |
|
dc.contributor.author |
Novikov V. |
|
dc.contributor.author |
Solomonov A. |
|
dc.date.accessioned |
2018-09-17T21:25:29Z |
|
dc.date.available |
2018-09-17T21:25:29Z |
|
dc.date.issued |
2002 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134973 |
|
dc.description.abstract |
The applicability of the approach based on the linear solvation energy relationship to describing the enthalpies of specific solvent-solute interactions was examined. In associated solvents, this approach reflects the contribution of specific interaction incorrectly. Although the enthalpies of solvation as a whole are described well, this is an "occasional" result and is due to averaging over different compounds and redistribution of contributions from other types of interactions. A modification of this approach was suggested to take into account the effect of reorganization of an associated solvent. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.title |
Multiparameter correlations for describing thermodynamic parameters of solvation: II. Enthalpy of specific interaction |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
7 |
|
dc.relation.ispartofseries-volume |
72 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1053 |
|
dc.source.id |
SCOPUS10703632-2002-72-7-SID0036035203 |
|