Multiparameter correlations for description of thermodynamic parameters of solvation: I. Enthalpy of nonspecific solvation

Abstract

Applicability of a linear solvation-energy approach for descripition of the solvation enthalpies of nonelectrolytes is examined. In most cases a good fit of experimental solvation enthalpies can be attained. However, the resulting data are difficult to interpret in terms of different types of intermolecular interactions.