Solvent effect on the volume of the DielsAlder reaction between tetracyanoethylene and trans,trans-1,4-diphenyl-1,3-butadiene

dc.contributor.author	Kiselev V.
dc.contributor.author	Medvedeva M.
dc.contributor.author	Kashaeva E.
dc.contributor.author	Shikhaab M.
dc.contributor.author	Iskhakova G.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-17T21:25:12Z
dc.date.available	2018-09-17T21:25:12Z
dc.date.issued	2002
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134966
dc.description.abstract	From the partial molar volumes of tetracyanoethylene, trans,trans-1,4-diphenyl-1,3-butadiene, and their Diels-Alder adduct, the volumes of the reaction in a series of solvents at 25°C (cm3 mol-1) were calculated: in dioxane, -26.4; in chloroform, -34.9; in ethyl acetate, -34.5; in acetonitrile, -4.4; in cyclohexanone, -34.0; in 1,2-dichloroethane, -31.8; in benzene, -26.9; in toluene, -24.5; in o-xylene, -21.1; and in mesitylene, -16.9. The solvent effects on the activation and reaction volumes and on the partial molar volumes of the reactants, activated complex, and adduct were discussed.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Solvent effect on the volume of the DielsAlder reaction between tetracyanoethylene and trans,trans-1,4-diphenyl-1,3-butadiene
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	72
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	432
dc.source.id	SCOPUS10703632-2002-72-3-SID0036262007

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