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Electrochemical properties of crown-containing N-(thio)phosphoryl(thio)ureas and their complexes with 3d transition metals

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dc.contributor.author Shaidarova L.
dc.contributor.author Gedmina A.
dc.contributor.author Ulakhovich N.
dc.contributor.author Budnikov G.
dc.contributor.author Zabirov N.
dc.date.accessioned 2018-09-17T21:24:49Z
dc.date.available 2018-09-17T21:24:49Z
dc.date.issued 2002
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/134962
dc.description.abstract The electrochemical behavior of crown-containing N-(thio)phosphoryl(thio)ureas and their complexes with 3d transition metals was studied by dc voltammetry on a graphite electrode in acetone. Crown-containing N-(thio)phosphoryl(thio)ureas are not reduced but are oxidized on solid electrodes in the examined range of potentials; the electrons are transferred via the (thio)urea group. Electrooxidation of macrocyclic Co(II), Ni(II), and Cu(II) complexes probably occurs via formation of M(III) complex species. Electroreduction of these metal complexes involves stepwise electron transfer, with the oxidation state of the metal atom decreasing to 0, followed by dissociation of the electrochemical reaction products.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.title Electrochemical properties of crown-containing N-(thio)phosphoryl(thio)ureas and their complexes with 3d transition metals
dc.type Article
dc.relation.ispartofseries-issue 10
dc.relation.ispartofseries-volume 72
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1565
dc.source.id SCOPUS10703632-2002-72-10-SID0036989876


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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