Solvation and complex formation of nickel(II) with benzoic, p-chlorobenzoic, and p-methoxybenzoic hydrazides in aqueous-dioxane media

dc.contributor.author	Bychkova T.
dc.contributor.author	Shtyrlin V.
dc.contributor.author	Sadykova E.
dc.contributor.author	Zakharov A.
dc.contributor.author	Popova Y.
dc.date.accessioned	2018-09-17T21:24:37Z
dc.date.available	2018-09-17T21:24:37Z
dc.date.issued	2001
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134957
dc.description.abstract	Solvation and complex formation of nickel(II) with benzoic, p-chlorobenzoic, and p-methoxy-benzoic hydrazides in aqueous-dioxane media were studied. The mean coordination numbers of water and 1,4-dioxane in Ni(II) solvation complexes, the formation constants of mono- and biscomplexes of nickel(II) of the listed hydrazides at dioxane contents of 0-0.65 mole fraction, as well as the free energies of transfer of the ligands from water to aqueous-dioxane solvents were determined. An important role the basicity and solvation of the ligands play in te stability of Ni(II) complexes with benzoic hydrazides was demonstrated.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Solvation and complex formation of nickel(II) with benzoic, p-chlorobenzoic, and p-methoxybenzoic hydrazides in aqueous-dioxane media
dc.type	Article
dc.relation.ispartofseries-issue	6
dc.relation.ispartofseries-volume	71
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	926
dc.source.id	SCOPUS10703632-2001-71-6-SID0035541966

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.